Never knew that. I rarely make 10gallon/imperial beers. What causes it?
I'm not really sure.
The best I can think of is that its like rinsing a pot with soap in it. If you fill the pot with water and dump it, you get a certain amount of soap out. You fill it up again and you get more, but not all of the soap. There is still some left over. With unlimited water rinses, eventually you get the soap out. We don't have unlimited sparges.
My guess is that the bigger the batch, the more sugars there are per volume, and the more gets left over since you only have so much diluting power with your sparge since your boil volume is the same for a lower gravity batch and a higher gravity batch.
Edited by SchwanzBrewer, 18 June 2014 - 01:29 PM.