https://beerandwinej...form-a-blanket/
The blanket of CO2 atop an active fermentation is not a solid barrier. Gas diffusion is occurring constantly as CO2 diffuses into the air above it and oxygen (and nitrogen) dissolve into the region of high CO2 concentration. And, of course, a strong air current can blow this blanket away. It is the fact that CO2 is constantly being replaced that keeps the “CO2 blanket†intact during fermentation and able to protect the fermenting liquid from the vast majority of the oxygen exposure it would have suffered, if it had not been fermenting.
When I was using the plastic barrels to ferment 10 gal batches I was having a problem with appears to be acetaldehyde. It's was really annoying. I wasn't always prudent with getting the beer out of the fermenter very quickly after it was done fermenting and after it was cleared. I wonder if I was having air lock problems and was getting air intrusion into the fermenter post fermentation which was oxidizing the beer and during the clean up stage while there was still some active yeast, turning the ethanol back into acetaldehyde.
The last batch I fermented at home I used a big mouth bubbler, and I used vodka in the air lock instead of starsan. I ended up with acetaldehyde again. I let that one stay in the chamber longer than it should have and the vodka evaporated. This article suggests that the beer shouldn't be left in the fermenter because it has a CO2 blanket, when in actuality it doesn't after equilibrium has been reached - unless the air lock is true and there is no air left in the fermenter. Anecdotally this suppors what has happened to my beers over the last couple years at home.
I've not had any problems with acetaldehyde on the bigger system and I think it's because my air lock is better sealed and also because I slightly pressurize the fermenter (so I don't get a vacuum) and close it off completely when I cold crash.